A new application about 1-Aminopiperidine

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Reference of 2213-43-6, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.2213-43-6, Name is 1-Aminopiperidine, molecular formula is C5H12N2. In a Article£¬once mentioned of 2213-43-6

Synthesis and structure of novel rhodium complexes of multi-functionalised amine-phosphine ligands

The coordination behaviour of a variety of amine containing phosphine ligands has been studied. Two new multifunctionalised ligands have been prepared and shown along with three known ligands to favour a variety of coordination modes when complexed with rhodium(III) centres. The hemilabile PN chelate ligands show three different types of behaviour: strong P,N chelation even in the presence of chloride ions, strong P,N chelation after a chloride ligand is removed (Ag salts), and weak coordination after chloride abstraction. Five of the complexes have been characterised by X-ray crystallography. Multinuclear NMR and IR spectroscopies were also highly diagnostic in assigning the coordination chemistry favoured by each ligand.

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Reference£º
Piperidine – Wikipedia,
Piperidine | C5H820N – PubChem