Electric Literature of C5H14Cl2N2. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: (S)-Piperidin-3-amine dihydrochloride, is researched, Molecular C5H14Cl2N2, CAS is 334618-07-4, about Exploration of Chiral Organic-Inorganic Hybrid Semiconducting Lead Halides. Author is Peng, Yu; Yao, Yunpeng; Li, Lina; Liu, Xitao; Zhang, Xinyuan; Wu, Zhenyue; Wang, Sasa; Ji, Chengmin; Zhang, Weichuan; Luo, Junhua.
Organic-inorganic lead halides have recently emerged as promising alternatives to conventional optoelectronic materials, considering their intriguing phys. properties. However, organic-inorganic lead halides featuring chirality are seldom explored. Here, a pair of enantiomorphic organic-inorganic hybrid semiconducting lead halides, (R-C5H14N2)PbBr4 (1R) and (S-C5H14N2)PbBr4 (2S), were successfully obtained with the templating of chiral amines. These compounds adopt distinct one-dimensional infinite quantum helixes formed by edge-shared transformative lead bromide octahedra. Notably, 1R and 2S present mirror CD signals due to the chirality transfer of the enantiopure amines. Furthermore, 1R and 2S exhibit phase-matchable quadratic nonlinear response and typical semiconducting behaviors. This work highlights the potential of lead halides as a new kind of chiral semiconducting materials in spintronic and chiral optical applications.
《Exploration of Chiral Organic-Inorganic Hybrid Semiconducting Lead Halides》 provides a strategy for the preparation of materials with excellent comprehensive properties, which is conducive to broaden the application field of this compound((S)-Piperidin-3-amine dihydrochloride)Electric Literature of C5H14Cl2N2.
Reference:
Piperidine – Wikipedia,
Piperidine | C5H11N – PubChem