The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Iron(III) trifluoromethanesulfonate, is researched, Molecular C3F9FeO9S3, CAS is 63295-48-7, about Crystal structure of bis{(3,5-dimethylpyrazol-1-yl)dihydro[3-(pyridin-2-yl)pyrazol-1-yl]borato}iron(II), the main research direction is crystal structure bisdimethylpyrazolyl dihydropyridinyl pyrazolyl boratoiron; FeII; crystal structure; discrete complex.; dihydro(pyrazole)(pyridlypyrazole)borate derivative.Electric Literature of C3F9FeO9S3.
The structure determination of [Fe(C13H15BN5)2] was undertaken as part of a project on the modification of the recently published spin-crossover (SCO) complex [Fe{H2B(pz)(pypz)}2] (pz = pyrazole, pypz = pyridylpyrazole). To this end, a new ligand was synthesized in which two addnl. Me groups are present. Its reaction with iron trifluoromethanesulfonate led to a pure sample of the title compound, as proven by X-ray powder diffraction. The asym. unit consists of one complex mol. in a general position. The FeII atom is coordinated by two tridentate N-binding {H2B(3,5-(CH3)2-pz)(pypz)}- ligands. The Fe-N bond lengths range between 2.1222 (13) and 2.3255 (15) Å, compatible with FeII in the high-spin state, which was also confirmed by magnetic measurements. Other than a very weak C-H···N non-classical hydrogen bond linking individual mols. into rows extending parallel to [010], there are no remarkable intermol. interactions.
Different reactions of this compound(Iron(III) trifluoromethanesulfonate)Electric Literature of C3F9FeO9S3 require different conditions, so the reaction conditions are very important.
Reference:
Piperidine – Wikipedia,
Piperidine | C5H11N – PubChem