Synthetic Route of C3F9FeO9S3. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: Iron(III) trifluoromethanesulfonate, is researched, Molecular C3F9FeO9S3, CAS is 63295-48-7, about Metal triflate formation of C12-C22 phenolic compounds by the simultaneous C-O breaking and C-C coupling of benzyl phenyl ether. Author is Rahaman, Mohammad Shahinur; Tulaphol, Sarttrawut; Molley, Ashten; Mills, Kyle; Hossain, Anwar Md.; Yelle, Daniel; Maihom, Thana; Sathitsuksanoh, Noppadon.
Catalytic pathways to produce high carbon number compounds from benzyl Ph ether require multiple steps to break the aryl etheric carbon-oxygen bonds; these steps are followed by energy-intensive processes to remove oxygen atoms and/or carbon-carbon coupling. Here, we show an upgrading strategy to transform benzyl Ph ether into large phenolic (C12-C22) compounds by a one-step C-O breaking and C-C coupling catalyzed by metal triflates under a mild condition (100°C and 1 bar). Hafnium triflate was the most selective for the desired products. In addition, we measured the effect of solvent polarity on the catalytic performance. Solvents with a polarity index of less than 3.4 promoted the catalytic activity and selectivity to C12-C22 phenolic products. These C12-C22 phenolic compounds have potential applications for phenol-formaldehyde polymers, diesel/jet fuels, and liquid organic hydrogen carriers.
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Reference:
Piperidine – Wikipedia,
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