Electric Literature of C3F9FeO9S3. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Iron(III) trifluoromethanesulfonate, is researched, Molecular C3F9FeO9S3, CAS is 63295-48-7, about Hidden Bronsted Acid Catalysis: Pathways of Accidental or Deliberate Generation of Triflic Acid from Metal Triflates. Author is Dang, Tuan Thanh; Boeck, Florian; Hintermann, Lukas.
The generation of a hidden Bronsted acid as a true catalytic species in hydroalkoxylation reactions from metal precatalysts has been clarified in case studies. The mechanism of triflic acid (CF3SO3H or HOTf) generation starting either from AgOTf in 1,2-dichloroethane (DCE) or from a Cp*RuCl2/AgOTf/phosphane combination in toluene has been elucidated. The deliberate and controlled generation of HOTf from AgOTf and cocatalytic amounts of tert-Bu chloride in the cold or from AgOTf in DCE at elevated temperatures results in a hidden Bronsted acid catalyst useful for mechanistic control experiments or for synthetic applications.
This literature about this compound(63295-48-7)Electric Literature of C3F9FeO9S3has given us a lot of inspiration, and I hope that the research on this compound(Iron(III) trifluoromethanesulfonate) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Piperidine – Wikipedia,
Piperidine | C5H11N – PubChem