Application of 63295-48-7. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: Iron(III) trifluoromethanesulfonate, is researched, Molecular C3F9FeO9S3, CAS is 63295-48-7, about One-step Pd/C and Eu(OTf)3 catalyzed hydrodeoxygenation of branched C11 and C12 biomass-based furans to the corresponding alkanes. Author is Keskivali, Juha; Wrigstedt, Pauli; Lagerblom, Kalle; Repo, Timo.
Solvent-free NaOH catalyzed aldol condensation of biomass-derived 5-hydroxymethyl furfural (HMF) and furfural with Me iso-Bu ketone (MIBK) was studied, producing branched C11 and C12 furan compounds in high yields of up to 96%. Through use of a Pd/C and Eu(OTf)3 catalytic system, the condensation products of the bio-based starting materials were further hydrodeoxygenated (HDO) in one-step to biofuel compatible branched alkanes 2-methylundecane (3) and 2-methyldecane (4) in excellent yields of 90% and 98%, resp. In the one-step HDO developed herein, the variation of solvent had a significant effect on the reaction route and degree of conversion of furans to alkanes in the HDO process. Very high overall yields of alkanes 3 (86%) and 4 (94%) were obtained starting from the biomass-based HMF and furfural.
In addition to the literature in the link below, there is a lot of literature about this compound(Iron(III) trifluoromethanesulfonate)Application of 63295-48-7, illustrating the importance and wide applicability of this compound(63295-48-7).
Reference:
Piperidine – Wikipedia,
Piperidine | C5H11N – PubChem