So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Zhu, Nengbo; Zhao, Jianguo; Bao, Hongli researched the compound: Iron(III) trifluoromethanesulfonate( cas:63295-48-7 ).Product Details of 63295-48-7.They published the article 《Iron catalyzed methylation and ethylation of vinyl arenes》 about this compound( cas:63295-48-7 ) in Chemical Science. Keywords: aryl alkene alkyl peroxide iron catalyst alkylation; alkyl arylalkene diastereoselective preparation green chem. We’ll tell you more about this compound (cas:63295-48-7).
Iron-catalyzed Me, Et and Pr Heck reactions were developed using readily available alkyl peroxides as alkyl sources. The reaction conditions were mild, clean and easy to handle. No additive was needed and no hazardous waste was generated. The products were obtained in up to 99% yield of one isomer for most situations. This reaction works for many types of olefin and tolerates a variety of functional groups. Several late-stage functionalizations of natural products and drug mols. were conducted to demonstrate the synthetic applications of this reaction.
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