Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 175136-62-6, is researched, SMILESS is FC(C1=CC(C(F)(F)F)=CC(P(C2=CC(C(F)(F)F)=CC(C(F)(F)F)=C2)C3=CC(C(F)(F)F)=CC(C(F)(F)F)=C3)=C1)(F)F, Molecular C24H9F18PJournal, Article, Research Support, Non-U.S. Gov’t, Journal of the American Chemical Society called Modular Access to Azepines by Directed Carbonylative C-C Bond Activation of Aminocyclopropanes, Author is Wang, Gang-Wei; Bower, John F., the main research direction is azepine derivative preparation; benzazepine derivative preparation; aminocyclopropane preparation rhodium catalyzed heterocyclization carbonylative cyclization; sequential CC activation CH functionalization aminocyclopropane benzyloxycarbonyl derivatives; protecting group directed bond activation rhodium catalyzed heterocyclization aminocyclopropanes.Name: Tris(3,5-bis(trifluoromethyl)phenyl)phosphine.
A modular Rh-catalyzed entry to azepines is outlined. Under a CO atm., protecting group directed C-C bond activation of aminocyclopropanes provides rhodacyclopentanones. These intermediates are effective for intramol. C-H metalation of either an N-aryl or N-vinyl unit en route to azepine ring systems. Thus, byproduct-free heterocyclizations are enabled by sequential C-C activation and C-H functionalization steps.
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Reference:
Piperidine – Wikipedia,
Piperidine | C5H11N – PubChem