HPLC of Formula: 63295-48-7. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Iron(III) trifluoromethanesulfonate, is researched, Molecular C3F9FeO9S3, CAS is 63295-48-7, about Polymerization of 3-Undecylbithiophene and Preparation of Poly(3-undecylbithiophene)/Polystyrene Composites in Supercritical Carbon Dioxide. Author is Abbett, Kimberly F.; Teja, Amyn S.; Kowalik, Janusz; Tolbert, Laren.
The polymerization of 3-undecylbithiophene in supercritical carbon dioxide (with ferric triflate as the oxidant) was studied at 313 K and 10.5 MPa. The resulting polymer was comparable in structure, mol. weight, conjugation, and intrinsic elec. conductivity to the polymer synthesized in nitrobenzene (with ferric chloride as the oxidant). In addition, a 95% yield of the conducting polymer was obtained in 1 h. Conductive composites of poly(3-undecylbithiophene) and porous, crosslinked polystyrene were prepared via the in situ polymerization of 3-undecylbithiophene in supercritical carbon dioxide at temperatures in the range 313-413 K and pressures in the range 10.5-34.5 MPa. The highest conductivities of the composite were obtained at 313 K and 20.7 MPa, which represent optimum conditions for oxidant/monomer deposition and conducting polymer network formation on the surface and pores of the host polymer.
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