Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 175136-62-6, is researched, Molecular C24H9F18P, about Possible Origin of Electronic Effects in Rh(I)-Catalyzed Enantioselective Hydrogenation, the main research direction is electronic effect rhodium catalyzed enantioselective hydrogenation.Reference of Tris(3,5-bis(trifluoromethyl)phenyl)phosphine.
Reducing the electron d. of ligands switches the regioselectivity of Rh(I)-catalyzed hydrometalation. A reversal of the sense of chiral induction was also observed when chiral ligands are electronically tuned in the same manner. The combined data provide an alternative rationale for the electronic effects often observed in asym. hydrogenation.
There is still a lot of research devoted to this compound(SMILES：FC(C1=CC(C(F)(F)F)=CC(P(C2=CC(C(F)(F)F)=CC(C(F)(F)F)=C2)C3=CC(C(F)(F)F)=CC(C(F)(F)F)=C3)=C1)(F)F)Reference of Tris(3,5-bis(trifluoromethyl)phenyl)phosphine, and with the development of science, more effects of this compound(175136-62-6) can be discovered.
Reference:
Piperidine – Wikipedia,
Piperidine | C5H11N – PubChem