Application of 175136-62-6

If you want to learn more about this compound(Tris(3,5-bis(trifluoromethyl)phenyl)phosphine)Computed Properties of C24H9F18P, you may wish to communicate with the author of the article,or consult the relevant literature related to this compound(175136-62-6).

Computed Properties of C24H9F18P. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: Tris(3,5-bis(trifluoromethyl)phenyl)phosphine, is researched, Molecular C24H9F18P, CAS is 175136-62-6, about Transition-metal-catalyzed sequential cross-coupling of bis(iodozincio)methane and -ethane with two different organic halides. Author is Yoshino, Hideaki; Toda, Narihiro; Kobata, Masami; Ukai, Katsumi; Oshima, Koichiro; Utimoto, Kiitiro; Matsubara, Seijiro.

Bis(iodozincio)methane, prepared from diiodomethane and zinc, reacts with an organic halide in the presence of a transition-metal catalyst to give an iodozinciomethylenated compound; this then reacts with another organic halide to form a C-C bond. The overall process connects two electrophiles with one carbon atom. 1,1-Bis(iodozincio)ethane can also undergo this transformation, yielding a new stereogenic center. The asym. induction of this stereogenic center was investigated by using a chiral palladium catalyst.

If you want to learn more about this compound(Tris(3,5-bis(trifluoromethyl)phenyl)phosphine)Computed Properties of C24H9F18P, you may wish to communicate with the author of the article,or consult the relevant literature related to this compound(175136-62-6).

Reference:
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