50585-89-2, Methyl piperidine-3-carboxylate is a piperidines compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
50585-89-2, Potassium 3-methoxycarbonyl-piperidine-1-carbodithioate (13 Kmpc) was prepared by the dropwise addition of 14 CS2 (1.2mL, 20mmol) into a solution of methyl nipecotate (2.8mL, 20mmol) in 15 methanol (30mL) in the presence of 16 KOH (1.2g, 20mmol), stirring the reaction mixture for 1h. The yellow solid which separated was filtered off, washed with ethanol and thereafter with ether and dried (Scheme 2 ). Yield: 80%; m.p. 202C. Anal. Found: C, 37.15; H, 4.88; N, 5.70; S, 24.58%. Calc. for C8H12NO2S2K (257.40): C, 37.32; H, 4.70; N, 5.44; S, 24.91%. IR (KBr, cm-1): nu(C-H) 2944, 2857; nu(C=O) 1658; nu(CN) 1565; nu(C=S) 1012. 1H NMR (CDCl3: delta, ppm): 1.68-2.43 (m, H-3, H-4, H-5), 2.64 (t, 2H, H-6axial), 2.91 (d, 2H, H6-equatorial), 2.82 (t, 2H, H-2axial), 3.13 (d, 2H, H-2equatorial), 4.09 (s, 3H, -OCH3). 13C NMR (CDCl3: delta, ppm): 23.88-49.99 (piperidine ring), 51.01 (-OCH3), 173.50 (C=O), 212.46 (C=S).
The synthetic route of 50585-89-2 has been constantly updated, and we look forward to future research findings.
Reference£º
Article; Nath, Paras; Bharty; Kushawaha; Maiti; Polyhedron; vol. 151; (2018); p. 503 – 509;,
Piperidine – Wikipedia
Piperidine | C5H11N – PubChem