Application of 41979-39-9, The transformation of simple hydrocarbons into more complex and valuable products via catalytic C–H bond functionalisation has revolutionised modern synthetic chemistry. 41979-39-9, Name is Piperidin-4-one hydrochloride, SMILES is O=C1CCNCC1.[H]Cl, belongs to piperidines compound. In a article, author is Barton, Benita, introduce new discover of the category.
Complexes of TETROL with selected heterocyclics: unconventional host-guest hydrogen bonding and the correlation with host selectivity
Here we investigate and compare the more salient characteristics of host-guest complexes of (+)-(2R,3R)-1,1-4,4-tetraphenylbutane-1,2,3,4-tetraol (TETROL) with four heterocyclic guests, morpholine, piperidine, pyridine and dioxane. These guests each formed inclusion compounds with TETROL, and host:guest ratios were either 1:2 or 1:1. Single crystal diffraction experiments revealed unprecedented host behaviour in the presence of both piperidine and dioxane with respect to the mode of host-guest hydrogen bonding employed. Furthermore, by utilizing H-1-NMR spectroscopy or gas chromatography (as applicable) as methods for analysing complexes obtained from competition experiments, we were able to identify the host selectivity order, and were gratified to discover that this order correlated precisely with host-guest hydrogen bond distance.
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Reference:
Piperidine – Wikipedia,
,Piperidine | C5H11N – PubChem