Electric Literature of 38092-89-6, As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. 38092-89-6, Name is 8-Chloroazatadine, SMILES is CN1CC/C(CC1)=C2C3=CC=C(Cl)C=C3CCC4=CC=CN=C42, belongs to piperidines compound. In a article, author is Suzuki, Satoru, introduce new discover of the category.
Intramolecular Aminotrifluoromethanesulfinyloxylation of omega-Aminoalkenes by CF3SO2Na/Pd(OAc)(2)/PhI(OAc)(2)/(BuOCl)-Bu-t/PivOH System
The first example of palladium-catalyzed intramolecular aminotrifluoromethanesulfinyloxylation of unactivated omega-aminoalkenes has been achieved. Reaction conditions are rather unique with a complex consisting of CF3SO2Na/Pd(OAc)(2)/PhI(OAc)(2)/(BuOCl)-Bu-t/PivOH to provide 6-endo- cyclized type products with a piperidine skeleton. Yields are moderate, and SO2 is not extruded. This method also provides the first synthesis of 3-trifluoromethanesulfinyloxy piperidine derivatives.
Electric Literature of 38092-89-6, Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. I hope my blog about 38092-89-6 is helpful to your research.
Reference:
Piperidine – Wikipedia,
,Piperidine | C5H11N – PubChem