Chemistry, like all the natural sciences, begins with the direct observation of nature¡ª in this case, of matter.767-69-1, Name is 6-Bromo-7H-purine, SMILES is BrC1=NC=NC2=C1NC=N2, belongs to piperidines compound. In a document, author is Herold, Sebastian, introduce the new discover, Quality Control of 6-Bromo-7H-purine.
Anodic benzylic C(sp(3))-H amination: unified access to pyrrolidines and piperidines
An electrochemical aliphatic C-H amination strategy was developed to access the important heterocyclic motifs of pyrrolidines and piperidines within a uniform reaction protocol. The mechanism of this unprecedented C-H amination strategy involves anodic C-H activation to generate a benzylic cation, which is efficiently trapped by a nitrogen nucleophile. The applicability of the process is demonstrated for 40 examples comprising both 5- and 6-membered ring formations.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 767-69-1 is helpful to your research. Quality Control of 6-Bromo-7H-purine.
Reference:
Piperidine – Wikipedia,
,Piperidine | C5H11N – PubChem