Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, 5570-77-4, Name is 4-Chloro-1-methylpiperidine, SMILES is CN1CCC(CC1)Cl, in an article , author is Liu, Xiaojian, once mentioned of 5570-77-4, Quality Control of 4-Chloro-1-methylpiperidine.
Ligand-Controlled Regioselective Pd-Catalyzed Diamination of Alkenes
A ligand-controlled system has been disclosed for the regioselective palladium-catalyzed diamination of unactivated alkenes, which provides an easy access to a variety of aminofunctionalized piperidines and pyrrolidines. The steric hindrance of ligands controlled the regioselectivtities of products. 6-Endo diamination occurred with less sterically hindered quinox ligand to afford 3-aminopiperidines, while 5-exo diamination occurred with sterically bulky pyox ligand to give amino-substituted pyrrolidines.
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Reference:
Piperidine – Wikipedia,
,Piperidine | C5H11N – PubChem