The important role of 1-Phenylpiperidine-4-carbaldehyde

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Syntheses of Thyroliberin Analogues in which the C-Terminal Amide and the tau-Position of the Histidine Side-chain are Bridged. Regiospecific tau-im-Alkylation and 2-Hydroxyphenyl Ester Cyclopeptide Synthesis Exemplified

Syntheses of the bridged thyroliberin analogues pyroglutamyl-cyclo-N(tau)-(6-aminohex-1-yl)-histidylproline (1a) and pyroglutamyl-cyclo-N(tau)-(5-aminopent-1-yl)-histidylproline (1b) are described, exemplifying a novel method of regiospecific tau-im-alkylation and also cyclopeptide synthesis via 2-hydroxyphenylesters.

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Reference£º
Piperidine – Wikipedia,
Piperidine | C5H11718N – PubChem