Matsui, Ryosuke published the artcileConvergent Total Synthesis of (+)-TMC-151C by a Vinylogous Mukaiyama Aldol Reaction and Ring-Closing Metathesis, Formula: C11H15NOS, the publication is Angewandte Chemie, International Edition (2011), 50(3), 680-683, S680/1-S680/66, database is CAplus and MEDLINE.
Total synthesis of (+)-TMC-151C by a highly convergent synthetic route, is reported. Characteristic features of the present synthesis include the construction of the C1-C5 and C9-C13 units by vinylogous Mukaiyama aldol reactions and the use of a silicon-tethered diene for the stereoselective formation of the C6-C7 double bond by our recently developed E-selective ring-closing metathesis reaction to give an eight-membered ring. This synthetic strategy should provide efficient access to a range of related naturally occurring polyketides containing pent-2-ene-1,5-diol units.
Angewandte Chemie, International Edition published new progress about 4972-31-0. 4972-31-0 belongs to piperidines, auxiliary class Piperidine,Benzene, name is 1-(Phenylsulfinyl)piperidine, and the molecular formula is C11H15NOS, Formula: C11H15NOS.
Referemce:
https://en.wikipedia.org/wiki/Piperidine,
Piperidine | C5H11N – PubChem