D’Amato, Erica M.’s team published research in Organometallics in 34 | CAS: 219543-09-6

Organometallics published new progress about 219543-09-6. 219543-09-6 belongs to piperidines, auxiliary class Piperidine,Fluoride,Salt,Amine,Amide, name is 4-Acetamido-2,2,6,6-tetramethyl-1-oxopiperidinium Tetrafluoroborate, and the molecular formula is C11H21BF4N2O2, Formula: C11H21BF4N2O2.

D’Amato, Erica M. published the artcileSelective Aromatic C-H Hydroxylation Enabled by η6-Coordination to Iridium(III), Formula: C11H21BF4N2O2, the publication is Organometallics (2015), 34(18), 4626-4631, database is CAplus and MEDLINE.

Authors report here an aromatic C-H hydroxylation protocol in which the arene is activated through η6-coordination to an iridium(III) complex. η6-Coordination of the arene increases its electrophilicity and allows for high positional selectivity of hydroxylation at the site of least electron d. Through investigation of intermediate η5-cyclohexadienyl adducts and arene exchange reactions, it was evaluated that incorporation of arene π-activation into a catalytic cycle for C-H functionalization.

Organometallics published new progress about 219543-09-6. 219543-09-6 belongs to piperidines, auxiliary class Piperidine,Fluoride,Salt,Amine,Amide, name is 4-Acetamido-2,2,6,6-tetramethyl-1-oxopiperidinium Tetrafluoroborate, and the molecular formula is C11H21BF4N2O2, Formula: C11H21BF4N2O2.

Referemce:
https://en.wikipedia.org/wiki/Piperidine,
Piperidine | C5H11N – PubChem