Mao, Shuhua published the artcile(RuBpy3)2+-bisterpyridinyl triangle promoted singlet oxygen (1O2) photosensitization for fast oxidation of sulfur mustard simulant, Quality Control of 826-36-8, the publication is Inorganic Chemistry Communications (2022), 109090, database is CAplus.
(RuBpy3)2+-bisterpyridine-based metallacycle T photosensitizer was prepared by a facile single-step self-assembly process. Supramol. self-assembly strategy greatly improved metallacycle T’s photosensitized ability due to its enhanced light-harvesting capability, smaller energy gap (ΔEST) between lowest excited singlet state (S1) and lowest excited triplet state (T1) along with excellent solubility which exhibiting higher efficiency for singlet oxygen (1O2) production than the ligand L and its pendant [(RuBpy3)2+·2PF6–]. In the practical photo-driven degradation of sulfur mustard simulant (2-chloroethyl Et sulfide, CEES), full conversion of toxic CEES to nontoxic CEESO was achieved by metallacycle T with an extremely fast lifetime of 90 s (half lifetime t1/2 = 25 s) and 100% selectivity (without formation of highly toxic CEESO2), while ligand L and [(RuBpy3)2+·2PF6–] needed 130 s and 330 s, resp. This study demonstrated terpyridine-based novel supermols. can serve as efficient scaffolds for effective enhancement of photosensitization.
Inorganic Chemistry Communications published new progress about 826-36-8. 826-36-8 belongs to piperidines, auxiliary class Natural product, name is 2,2,6,6-Tetramethylpiperidin-4-one, and the molecular formula is C9H17NO, Quality Control of 826-36-8.
Referemce:
https://en.wikipedia.org/wiki/Piperidine,
Piperidine | C5H11N – PubChem