Tomoda, Shuji published the artcileOrigin of π-facial diastereoselection in hydride reduction of piperidones. The importance of ground-state effects, Recommanded Product: 3-Methylpiperidin-4-one, the main research area is facial stereoselectivity hydride reduction piperidinone FMO steric effect.
The exterior frontier orbital extension model (the EFOE Model) strongly suggested that the ground-state conformation (steric effects) and the anisotropic frontier orbital (LUMO) extension over π-faces may be the origin of the π-facial diastereoselection in hydride reductions of substituted piperidones.
Chemistry Letters published new progress about Conformation. 5773-58-0 belongs to class piperidines, name is 3-Methylpiperidin-4-one, and the molecular formula is C6H11NO, Recommanded Product: 3-Methylpiperidin-4-one.
Referemce:
Piperidine – Wikipedia,
Piperidine | C5H11N – PubChem