Yakukhnov, Sergey A. published the artcileCatalytic Transfer Hydrodebenzylation with Low Palladium Loading, Category: piperidines, the main research area is benzyl ester palladium catalyst hydrodebenzylation; ether benzyl palladium catalyst hydrodebenzylation; amine benzyl palladium catalyst hydrodebenzylation; aryl halide palladium catalyst hydrodehalogenation.
A highly-efficient catalytic system for hydrodebenzylation is described. The cleavage of O-benzyl and N-benzyl protecting groups was performed using an uncommonly low palladium loading (0.02-0.3 mol%; TON up to 5000) in a relatively short reaction time. This approach was used for a variety of substrates including pharmaceutically important precursors, and gram-scale deprotection was demonstrated. Transfer conditions and an easy-to-make Pd/C catalyst are key features of this debenzylation scheme.
Advanced Synthesis & Catalysis published new progress about Aromatic hydrocarbons Role: SPN (Synthetic Preparation), PREP (Preparation). 73874-95-0 belongs to class piperidines, name is tert-Butyl piperidin-4-ylcarbamate, and the molecular formula is C10H20N2O2, Category: piperidines.
Referemce:
Piperidine – Wikipedia,
Piperidine | C5H11N – PubChem