On September 19, 2022, Zhang, Ke; Ren, Bai-Hao; Liu, Xiao-Fei; Wang, Lin-Lin; Zhang, Min; Ren, Wei-Min; Lu, Xiao-Bing; Zhang, Wen-Zhen published an article.Product Details of 39512-49-7 The title of the article was Direct and Selective Electrocarboxylation of Styrene Oxides with CO2 for Accessing β-Hydroxy Acids. And the article contained the following:
Highly selective and direct electroreductive ring-opening carboxylation of epoxides with CO2 in an undivided cell was reported. This reaction showed broad substrate scopes within styrene oxides under mild conditions, providing practical and scalable access to important synthetic intermediate β-hydroxy acids. Mechanistic studies show that CO2 functions not only as a carboxylative reagent in this reaction but also as a promoter to enable efficient and chemoselective transformation of epoxides under additive-free electrochem. conditions. Cathodically generated α-radical and α-carbanion intermediates leaded to the regioselective formation of α-carboxylation products. The experimental process involved the reaction of 4-(4-Chlorophenyl)piperidin-4-ol(cas: 39512-49-7).Product Details of 39512-49-7
The Article related to epoxide carbon dioxide regioselective chemoselective electroreductive ring opening carboxylation, hydroxyalkyl carboxylic acid preparation, carbon dioxide fixation, carboxylation, epoxides, hydroxy acids, organic electrosynthesis and other aspects.Product Details of 39512-49-7
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Piperidine – Wikipedia,
Piperidine | C5H11N – PubChem