Synthetic Route of C6H11NOIn 2022 ,《Supported Anionic Gold Nanoparticle Catalysts Modified Using Highly Negatively Charged Multivacant Polyoxometalates》 was published in Angewandte Chemie, International Edition. The article was written by Xia, Kang; Yatabe, Takafumi; Yonesato, Kentaro; Yabe, Tomohiro; Kikkawa, Soichi; Yamazoe, Seiji; Nakata, Ayako; Yamaguchi, Kazuya; Suzuki, Kosuke. The article contains the following contents:
Although supported anionic gold nanoparticle catalysts have been theor. investigated for their efficacy in activating O2 in aerobic oxidation reactions, limited studies have been reported due to the difficulty of designing these catalysts. Herein, we developed a feasible method for preparing supported anionic gold nanoparticle catalysts using multivacant lacunary polyoxometalates with high neg. charges. We confirmed the strong and robust electronic interaction between gold nanoparticles and multivacant lacunary polyoxometalates, and the electronic states of the supported gold nanoparticle catalysts can be sequentially modulated. Particularly, the catalyst prepared using [SiW9O34]10- acted as an efficient reusable heterogeneous catalyst, showing superior catalytic performance for the oxidative dehydrogenation of piperidone derivatives to the corresponding enaminones and remarkably higher stability than supported gold nanoparticle catalysts without this modification. In the part of experimental materials, we found many familiar compounds, such as 1-Methyl-4-piperidone(cas: 1445-73-4Synthetic Route of C6H11NO)
1-Methyl-4-piperidone(cas: 1445-73-4) is a member of piperidine. Piperidine-containing compounds are also frequently employed in synthesis as ligands or auxiliaries. Accordingly, many efforts have been devoted to the development of novel methods for the synthesis of these compounds over the years.Synthetic Route of C6H11NO
Referemce:
Piperidine – Wikipedia,
Piperidine | C5H11N – PubChem