Chemistry is an experimental science, Quality Control of: Methyl 1-benzylpiperidine-3-carboxylate, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 50585-91-6, Name is Methyl 1-benzylpiperidine-3-carboxylate
The alternating current electrochemical synthesis starting from ethanol solution of Cu(ClO4)2·6H2O, CuSO 4·5H2O and Cu(BF4)2· 6H2O with the equimolar mixture of 1- and 2-allylbenzotriazole (all-bta) has led to a formation of Cu[2-all-bta]ClO4 (I), Cu[2-all-bta]HSO4 (II) and Cu[2-all-bta]BF4·H 2O (III) compounds. The direct interaction between Cu(ClO 4)2·6H2O and the mixture of 1- and 2-allylbenzotriazole in ethanol solution results in an appearance of Cu[(1-all-bta)(2-all-bta)]ClO4 (IV) compound. These results are strikingly different from earlier performed syntheses using the same ligands mixture and copper(II) halides, and producing coordination compounds with 1-allylbenzotriazole only. Compounds I and II are isotypical and crystallize in a monoclinic space group Cc. I: a = 9.5413(10) , b = 12.3171(9) , c = 10.3264(10) , beta = 111.155(4), V = 1131.78(18) 3, Z = 4. II: a = 9.1707(17) , b = 13.6639(17) , c = 9.4543(17) , beta = 105.555(7), V = 1141.3(3) 3, Z = 4. The main feature of structures I and II is a chelate-bridging role of the ligand moiety, bonded to one copper ion via CC-bond of the allyl group and nitrogen atom of the triazole core, and to the second Cu+ centre by another N atom. Trigonal-pyramidal copper environment comprises of two nitrogen atoms from different ligand units, CC-bond and oxygen atom at the apical position. The bridging function of both Cu+ cations and 2-all-bta molecules results in the formation of infinite chains. High affinity of BF4- anion to the H2O leads to a formation of compound III including water molecule. It crystallizes in an orthorhombic Pbca space group, a = 13.502(8) b = 11.299(5) c = 16.124(8) , V = 2460(2) 3, Z = 8. The ligand moiety plays the same as in I and II chelate-bridging function, but Cu+, being also bonded to CC group and to two N atoms, is connected with the disordered BF4- anion through the water bridge. In the crystal structure IV the metal ion possesses mixed-isomer surrounding, being bound to N-atom and CC-bond of 2-all-bta molecule, N-atom of 1-all-bta-moiety and O(ClO4 -) atom at apical position. IR spectra confirm rather effective Cu-(CC) bonding.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. Quality Control of: Methyl 1-benzylpiperidine-3-carboxylate, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 50585-91-6, in my other articles.
Reference：
Piperidine – Wikipedia,
Piperidine | C5H18910N – PubChem