Day: March 28, 2022

The reaction of an aromatic heterocycle with a proton is called a protonation. One of articles about this theory is 《Use of weak-perturbing radio-frequency fields in nuclear magnetic double resonance》. Authors are Freeman, R.; Anderson, W. A..The article about the compound:2,3-Dibromopropionic acidcas:600-05-5,SMILESS:O=C(O)C(Br)CBr).Category: piperidines. Through the article, more information about this compound (cas:600-05-5) is conveyed.

A theory is developed to explain high-resolution nuclear magnetic resonance spectra observed in the presence of a 2nd weak radio-frequency field at ω2. When ω2 is set on a nondegenerate transition frequency and the rest of the spectrum recorded by sweeping the frequency of the investigating radio-frequency field, any transitions that have an energy level in common with the perturbed transition will be split into doublets. If magnetic field inhomogeneities exceed the natural line width, the line profile of the doublets gives information about the ordering of the 3 energy levels involved. Good agreement with the theory was obtained in experiments on 2-spin and 3-spin proton systems where the energy-level diagram is already known. The method was used to establish the ordering of the energy levels of the ABC system of protons in methyltrivinylsilane and the analysis was completed by 2 independent methods. Some of the special effects which arise when double-resonance spectra are recorded by sweeping the magnetic field were examined and discussed.

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Reference:
Piperidine – Wikipedia,
Piperidine | C5H11N – PubChem

Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Article, Research Support, Non-U.S. Gov’t, Journal of Magnetic Resonance called Accurate measurement of small heteronuclear coupling constants from pure-phase α/β HSQMBC cross-peaks, Author is Gil, Sergi; Espinosa, Juan Felix; Parella, Teodor, which mentions a compound: 600-05-5, SMILESS is O=C(O)C(Br)CBr, Molecular C3H4Br2O2, SDS of cas: 600-05-5.

A simple proton-selective α/β-HSQMBC experiment is proposed for the accurate measurement of long-range proton-carbon coupling constants (n J CH) in small mols. without need for an individualized and time-consuming post-processing fitting procedure. The method acquires two pure-phase In-phase (IP) and Anti-phase (AP) multiplets completely free of any phase distortion due to the absence of J HH evolution. Accurate n J CH values can be directly measured analyzing the relative displacement of the resulting IPAP cross-peaks. Discussion about signal intensity dependence and cross-talk is made for a range of exptl. conditions. The robustness of the method is evaluated by comparing the n J CH value measured from the anal. of the three available IP, AP and IPAP multiplet patterns. Multiple-frequency and region-selective versions of the method can also be efficiently recorded provided that excited protons are not mutually coupled.

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Reference:
Piperidine – Wikipedia,
Piperidine | C5H11N – PubChem

Reference of Iron(III) trifluoromethanesulfonate. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: Iron(III) trifluoromethanesulfonate, is researched, Molecular C3F9FeO9S3, CAS is 63295-48-7, about Clean production of ethyl levulinate from kitchen waste. Author is Tian, Lu; Zhang, Luxin; Liu, Yuting; He, Yunfei; Zhu, Yujie; Sun, Ruijun; Yi, Simin; Xiang, Junping.

A clean and highly efficient catalytic system for the synthesis of Et levulinate (EL) from kitchen waste was developed. A heterogeneous catalyst (Sn/ZrP-SO3H) was prepared and the Bronsted and Lewis acid sites on the surface of the catalyst were evaluated by pyridine FT-IR. Other physicochem. properties were also characterized using XRD, SEM, FT-IR, XPS, BET, NH3-TPD. The yield of EL obtained was 49.27%, when glucose was used as the starting material and subjected to 170°C for 10 h in the presence of the solid acid catalyst, Sn/ZrP-SO3H. The prepared catalyst was also combined with several metal triflates; (Al(OTf)3, Fe(OTf)3, Sm(OTf)3) to form a catalytic system for the efficient preparation of EL from kitchen waste. Sn/ZrP-SO3H/Al(OTf)3 had superior activity compare to other catalyst combinations. In single factor experiments, the yield of EL reached 52.52% after heating at 170°C for 4 h. In addition, four-factor and three-level experiments were performed using response surface methodol. (RSM) to analyze the interaction between each factor. The optimal reaction conditions predicted by the model (163°C, 7.63 h, 20 mg Al(OTf)3, 40 mg Sn/ZrP-SO3H and 79.98 mg of kitchen waste) estimated a maximal yield for EL of 51.24%. The exptl. yield of EL however was 52.03% which confirms the reliability of the model. This work provides a cleaner production technol. for the synthesis of the high value-added chem. EL, and a sustainable route for the utilization of kitchen waste.

Here is a brief introduction to this compound(63295-48-7)Reference of Iron(III) trifluoromethanesulfonate, if you want to know about other compounds related to this compound(63295-48-7), you can read my other articles.

Reference:
Piperidine – Wikipedia,
Piperidine | C5H11N – PubChem

COA of Formula: C3F9FeO9S3. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: Iron(III) trifluoromethanesulfonate, is researched, Molecular C3F9FeO9S3, CAS is 63295-48-7, about Asymmetric tetranuclear nickel chains with unidirectionally ordered 2-(α-(5-phenyl)pyridylamino)-1,8-naphthyridine ligands. Author is Tsou, Lien-Hung; Sigrist, Marc; Chiang, Ming-Hsi; Horng, Er-Chien; Chen, Chun-hsien; Huang, Shou-Ling; Lee, Gene-Hsiang; Peng, Shie-Ming.

The new ligand, 2-(α-(5-phenyl)pyridylamino)-1,8-naphthyridine (Hphpyany), was synthesized by a Pd(0)-catalyzed reaction of 2-chloro-1,8-naphthyridine with 2-amino-5-phenylpyridine in the presence of potassium tert-butoxide. Linear tetranickel metal complexes, [Ni4(phpyany)4Cl2](CF3SO3) 1, [Ni4(phpyany)4Cl2](BF4)2 2, [Ni4(phpyany)4(NCS)2](ClO4) 3 and [Ni4(phpyany)4(NCS)2](CF3SO3)2 4 were prepared and crystallog. characterized. Complexes 1-4 demonstrate that, for the first time, four asym. ligands align unidirectionally and thus configure (4,0)-form tetranickel strings, specifically, with the Ph groups of the four phpyany- pointing to one side of the Ni4 chain and naphthyridyl to the other. The remarkably short Ni-Ni distances (∼2.33 Å) for 1 and 3 indicate partial metal-metal bonding, which can be viewed as both complexes containing one mixed-valence Ni23+ unit. The measurements of the magnetic susceptibility reveal that Ni47+ complexes 1 and 3 exhibit antiferromagnetic interactions (J = -42 cm-1 for 1 and -46 cm-1 for 3) between the terminal Ni2+ ion and the Ni23+ unit, while Ni48+ complexes 2 and 4 exhibit antiferromagnetic interactions (J = -33 cm-1 for 2 and -35 cm-1 for 4) between the two terminal Ni2+ ions. The results of the cyclic voltammetry indicate two reversible redox couples at E1/2(1) = 0.12 V, E1/2(2) = -0.65 V for 1, and at E1/2(1) = 0.12 V, E1/2(2) = -0.72 V for 3. The products of the first oxidation for 1 and 3 are the oxidized dication species 2 and 4, resp. The values of single-mol. resistance (15.4 (±3.46) MΩ for 3 and 16.2 (±5.04) MΩ for 4) were determined by STM-based break-junction methods. The results represent the first conductance measurements of linear tetranickel chains.

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Reference:
Piperidine – Wikipedia,
Piperidine | C5H11N – PubChem

The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Tris(3,5-bis(trifluoromethyl)phenyl)phosphine(SMILESS: FC(C1=CC(C(F)(F)F)=CC(P(C2=CC(C(F)(F)F)=CC(C(F)(F)F)=C2)C3=CC(C(F)(F)F)=CC(C(F)(F)F)=C3)=C1)(F)F,cas:175136-62-6) is researched.COA of Formula: C7H7NO. The article 《Enhanced regioselectivity of rhodium-catalyzed alkene hydroboration in supercritical carbon dioxide》 in relation to this compound, is published in Chemical Communications (Cambridge). Let’s take a look at the latest research on this compound (cas:175136-62-6).

Catalyzed alkene hydroboration proceeds in supercritical CO2 with several rhodium(I) complexes using tunable fluorinated ligands and shows higher regioselectivity relative to THF or perfluoromethylcyclohexane. The catalyzed hydroboration of 4-vinylanisole and α- and β-methylstyrene is reported.

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Reference:
Piperidine – Wikipedia,
Piperidine | C5H11N – PubChem